This book provides a State of the Art Report (STAR) produced by RILEM Technical Committee 254-CMS ‘Thermal Cracking of Mas-sive Concrete Structures’. Several recent developments related to the old problem of understanding/predicting stresses originated from the evolution of the hydration of concrete are at the origin of the creation this technical committee. Having identified a lack in the organization of up-to-date scientific and technological knowledge about cracking induced by hydration heat effects, this STAR aims to provide both practitioners and scientists with a deep integrated overview of consolidated knowledge, together with recent developments on this subject.